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Water samples were collected from 63 wells in southern New Castle County to assess the occurrence and distribution of dissolved inorganic chemicals in ground water. Rapid growth is projected for the study area, and suitable sources of potable drinking water will need to be developed. The growth in the study area could also result in degradation of water quality. This report documents water quality during 1991-92 and provides evidence for the major geochemical processes that control the water quality.